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The “soluble thiolome” is illustrated in Scheme 1 and operationally defined as the metabolic grid centered on the flux of the sulphur-containing amino acid cysteine ( 1a ), on the production of the anabolic intermediate γ-glutamyl-cysteine ( 2a ), of the abundant (pseudo-)peptide glutathione ( 3a ) and of its catabolic product cysteinyl-glycine ( 4a )